Lanthanides and Actinides in Molecular Magnetism.
The first reference on this rapidly growing topic provides an essential up-to-date guide to current and emerging trends. A group of international experts has been carefully selected by the editors to cover all the central aspects, with a focus on molecular species while also including industrial app...
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Format: | Electronic eBook |
Language: | English |
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Hoboken :
Wiley,
2015.
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100 | 1 | |a Layfield, Richard. | |
245 | 1 | 0 | |a Lanthanides and Actinides in Molecular Magnetism. |
260 | |a Hoboken : |b Wiley, |c 2015. | ||
300 | |a 1 online resource (367 pages) | ||
336 | |a text |b txt |2 rdacontent | ||
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500 | |a 4.3.2.1 Chains Based on 4f Ions. | ||
505 | 0 | |a Lanthanides and Actinides in Molecular Magnetism; Contents; Preface; List of Contributors; Chapter 1 Electronic Structure and Magnetic Properties of Lanthanide Molecular Complexes; 1.1 Introduction; 1.2 Free Ion Electronic Structure; 1.2.1 Free Ion Magnetism; 1.3 Electronic Structure of Lanthanide Ions in a Ligand Field; 1.3.1 Stevens' Formalism; 1.3.2 Wybourne's Formalism; 1.3.3 Standardization; 1.3.4 Calculation of Crystal Field Parameters; 1.4 Magnetic Properties of Isolated Lanthanide Ions; 1.4.1 Effect of a Magnetic Field; 1.4.2 EPR Spectroscopy of Lanthanide Complexes. | |
505 | 8 | |a 1.5 Exchange Coupling in Systems Containing Orbitally Degenerate LanthanidesAcknowledgements; References; Chapter 2 Mononuclear Lanthanide Complexes: Use of the Crystal Field Theory to Design Single-Ion Magnets and Spin Qubits; 2.1 Introduction; 2.2 Modelling the Magnetic Properties of Lanthanide Single-Ion Magnets: The Use of the Crystal Field Model; 2.2.1 Theoretical Background; 2.2.2 How to Determine the Crystal-Field Parameters: 1. The Ishikawa Approach; 2.2.3 How to Determine the Crystal-Field Parameters: 2. The Point Charge Electrostatic Model. | |
505 | 8 | |a 2.2.4 How to Determine the Crystal-Field Parameters: 3. The Effective Point Charge Model2.3 Magneto-Structural Correlations for Some Typical Symmetries; 2.4 Impact of Lanthanide Complexes in Quantum Computing; 2.4.1 Quantum Computing Paradigms and Design Criteria; 2.4.2 Combining Physical Qubit Implementations with Lanthanide Complexes; 2.4.3 Molecular Spin Qubits; 2.5 Conclusions; Acknowledgements; References; Chapter 3 Polynuclear Lanthanide Single Molecule Magnets; 3.1 Introduction; 3.2 Synthetic Strategies; 3.2.1 Dy3 Triangles and Their Derivatives; 3.2.1.1 Seminal Dy3 Triangle. | |
505 | 8 | |6 880-01 |a 3.2.6 The Organometallic Synthesis -- A New Approach3.3 Conclusion; References; Chapter 4 Lanthanides in Extended Molecular Networks; 4.1 Introduction; 4.2 Extended Networks Based on Gd3+; 4.2.1 Metal-Organic Frameworks; 4.2.1.1 Magneto-Caloric Effect; 4.2.1.2 Slow Magnetic Relaxation and Phonon Bottleneck Effects; 4.2.2 Magnetic Chains; 4.2.2.1 Magnetic Interactions Involving Gd3+ Ions; 4.2.2.2 Gadolinium-Radical Chains; 4.3 Extended Networks Based on Anisotropic Ions; 4.3.1 SCM in a Nutshell; 4.3.2 An Overview of Monodimensional Lanthanide Chains Based on Anisotropic Ions. | |
520 | |a The first reference on this rapidly growing topic provides an essential up-to-date guide to current and emerging trends. A group of international experts has been carefully selected by the editors to cover all the central aspects, with a focus on molecular species while also including industrial applications. The resulting unique overview is a must-have for researchers, both in academia and industry, who are entering or already working in the field. | ||
588 | 0 | |a Print version record. | |
650 | 0 | |a Rare earth metals. | |
650 | 0 | |a Actinide elements. | |
650 | 2 | |a Metals, Rare Earth | |
650 | 2 | |a Actinoid Series Elements | |
700 | 1 | |a Murugesu, Muralee. | |
758 | |i has work: |a Lanthanides and Actinides in Molecular Magnetism (Text) |1 https://id.oclc.org/worldcat/entity/E39PCFxkmCVrJVmX8xQf9QDKBP |4 https://id.oclc.org/worldcat/ontology/hasWork | ||
776 | 0 | 8 | |i Print version: |a Layfield, Richard. |t Lanthanides and Actinides in Molecular Magnetism. |d Hoboken : Wiley, ©2015 |z 9783527335268 |
852 | |b Online |h ProQuest | ||
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880 | 8 | |6 505-01/(S |a 3.2.1.2 Other Triangular Dy3 Systems3.2.1.3 The Coupling of Dy3 Triangles; 3.2.2 Linear Polynuclear Lanthanide Complexes Showing Robust SMM Behaviour; 3.2.2.1 Linear Dy3 SMMs; 3.2.2.2 Linear Dy4 SMMs; 3.2.3 Planar Dy4 SMMs; 3.2.4 Dyn SMMs Having Multiple μn-O (n>4) Bridges; 3.2.4.1 The Dy4 Grids Fixed by μ4-O Atom; 3.2.4.2 The Dy4 Tetrahedron Fixed by μ4-O Atom; 3.2.4.3 The Dy5 Pyramid Fixed by μ5-O Atom; 3.2.5 Hydrazone-Based Lanthanide SMMs; 3.2.5.1 The Assembly of Dy6 Triangular Prism with Dy2 Units; 3.2.5.2 A Dy3 Molecular Cluster Pair (Dy6). | |
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