Mass Spectrometry in Polymer Chemistry.
Combining an up-to-date insight into mass-spectrometric polymer analysis beyond MALDI with application details of the instrumentation, this is a balanced and thorough presentation of the most important and widely used mass-spectrometric methods. Written by the world's most proficient experts in...
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| Format: | Electronic eBook |
| Language: | English |
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Hoboken :
John Wiley & Sons,
2011.
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| Online Access: |
Full text (Emmanuel users only) |
Table of Contents:
- Mass Spectrometry in Polymer Chemistry; Contents; List of Contributors; Introduction; 1 Mass Analysis; 1.1 Introduction; 1.2 Measures of Performance; 1.2.1 Mass Resolving Power; 1.2.2 Mass Accuracy; 1.2.3 Mass Range; 1.2.4 Linear Dynamic Range; 1.2.5 Abundance Sensitivity; 1.3 Instrumentation; 1.3.1 Sector Mass Analyzers; 1.3.2 Quadrupole Mass Filters; 1.3.3 3D Ion Traps; 1.3.4 Linear Ion Traps; 1.3.5 Time-of-Flight Mass Analyzers; 1.3.6 Fourier Transform Ion Cyclotron Resonance Mass Analyzers; 1.3.7 Orbitraps; 1.4 Instrumentation in Tandem and Multiple-Stage Mass Spectrometry.
- 1.5 Conclusions and OutlookReferences; 2 Ionization Techniques for Polymer Mass Spectrometry; 2.1 Introduction; 2.2 Small Molecule Ionization Era; 2.2.1 Electron Ionization (EI); 2.2.2 Chemical Ionization (CI); 2.2.3 Pyrolysis Mass Spectrometry (Py-MS); 2.3 Macromass Era of Ionization; 2.3.1 Field Desorption (FD) and Field Ionization (FI); 2.3.2 Secondary Ion Mass Spectrometry (SIMS); 2.3.3 Fast Atom Bombardment (FAB) and Liquid Secondary Ion Mass Spectrometry (LSIMS); 2.3.4 Laser Desorption (LD); 2.3.5 Plasma Desorption (PD); 2.3.6 Other Ionization Methods.
- 2.4 Modern Era of Ionization Techniques2.4.1 Electrospray Ionization (ESI); 2.4.2 New Trends; 2.4.3 Atmospheric Pressure Chemical Ionization (APCI); 2.4.4 New Trends; 2.4.5 Matrix-Assisted Laser Desorption/Ionization (MALDI); 2.4.6 New Trends; 2.5 Conclusions; References; 3 Tandem Mass Spectrometry Analysis of Polymer Structures and Architectures; 3.1 Introduction; 3.2 Activation Methods; 3.2.1 Collisionally Activated Dissociation (CAD); 3.2.2 Surface-Induced Dissociation (SID); 3.2.3 Photodissociation Methods; 3.2.4 Electron Capture Dissociation and Electron Transfer Dissociation (ECD/ETD).
- 3.2.5 Post-Source Decay (PSD)3.3 Instrumentation; 3.3.1 Quadrupole Ion Trap (QIT) Mass Spectrometers; 3.3.2 Quadrupole/time-of-flight (Q/ToF) Mass Spectrometers; 3.3.3 ToF/ToF Instruments; 3.4 Structural Information from MS2 Studies; 3.4.1 End-Group Analysis and Isomer/Isobar Differentiation; 3.4.2 Polymer Architectures; 3.4.3 Copolymer Sequences; 3.4.4 Assessment of Intrinsic Stabilities and Binding Energies; 3.5 Summary and Outlook; References.
- 4 Matrix-Assisted Inlet Ionization and Solvent-Free Gas-Phase Separation Using Ion Mobility Spectrometry for Imaging and Electron Transfer Dissociation Mass Spectrometry of Polymers4.1 Overview; 4.2 Introduction; 4.3 New Sample Introduction Technologies; 4.3.1 Laserspray Ionization
- Ion Mobility Spectrometry-Mass Spectrometry; 4.3.2 Matrix Assisted Inlet Ionization (MAII); 4.3.3 LSIV in Reflection Geometry at Intermediate Pressure (IP); 4.4 Fragmentation by ETD and CID; 4.5 Surface Analyses by Imaging MS; 4.5.1 Ultraf Fast LSII-MS Imaging in Transmission Geometry (TG).